4.7 Article

Selective catalytic 2e--oxidation of organic substrates by an FeIIcomplex having an N-heterocyclic carbene ligand in water

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 68, Pages 9783-9786

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03289a

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Funding

  1. JST CREST [JPMJCR16P1, 15H00915, 17H03027, 18K19089]
  2. Japan Society of Promotion of Science (JSPS)
  3. Grants-in-Aid for Scientific Research [17H03027, 18K19089, 15H00915] Funding Source: KAKEN

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An Fe(II)complex,1, having a pentadentate ligand with an NHC moiety catalyzes substrate oxidation to afford 2e(-)-oxidized products with high selectivity by suppression of overoxidation in water. A Bell-Evance-Polanyi plot for the substrate oxidation catalyzed by1exhibited an inflection point around 86 kcal mol(-1), indicating strong C-H abstraction ability of the reactive species derived from1.

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