Journal
NEW JOURNAL OF CHEMISTRY
Volume 44, Issue 33, Pages 14067-14074Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nj01693d
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Funding
- Department of Science & Technology (DST), Government of India [DST/INSPIRE/04/2014/002251, IFA13/MS-36]
- DST [PDF/2017/001437]
- Centre of Nanosciences, Indian Institute of Technology, Kanpur
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Binary metal nitride nanorods of nickel-molybdenum nitride (Ni2Mo3N) are synthesized by a one-pot hydrothermal method followed by calcination at 400 degrees C and ammonolysis at 800 degrees C. The material is characterized by electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Ni2Mo3N nanorods are tested as an electrode material for supercapacitors and 264 C g(-1)specific capacity is exhibited at 0.5 A g(-1)current density with a specific capacity of 108 C g(-1)at high current density (5 A g(-1)), revealing 41% rate capability. The Ni2Mo3N electrode retained 81.4% of the specific capacity after 1000 cycles at 5 A g(-1)current density in the three-electrode system. A full cell device is constructed with Ni2Mo3N nanorods as the cathode, activated carbon (AC) as the anode, and porous cellulose paper as the separator in 6 M KOH electrolyte, and the Ni2Mo3N//AC asymmetric cell is assembled and exhibited a high specific capacity of 157 C g(-1)at 1 A g(-1)current density. Moreover, the asymmetric cell displayed an excellent cycling stability of 95.7% at a high current density (5 A g(-1)) after 3000 cycles and showed a maximum energy density of 34.89 W h kg(-1)at 800 W kg(-1)power density. The overall electrochemical performance of Ni2Mo3N nanorods in a supercapacitor is remarkable, suggesting an ideal candidate for future electrochemical devices.
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