Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 17, Pages 2576-2597Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00685h
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Funding
- National Natural Science Foundation of China [21702080]
- Open Project Program of Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Jiangxi Normal University [KLFS-KF-201603]
- foundation of Jiangxi Educational Committee [170223]
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Chiral cyclobutanes with quaternary stereogenic centers are motifs frequently found in various natural products and bioactive compounds. In addition, they are also useful intermediates for chemical synthesis, as they could undergo ring-expansion or ring-cleavage reactions to deliver various cyclic and acyclic chiral molecules. Therefore, the development of efficient catalytic methods for the highly enantioselective construction of chiral quaternary carbon containing cyclobutanes is of great synthetic value and has broad application prospects. The current review provides a summarization on the advances in catalytic asymmetric synthesis of quaternary carbon containing cyclobutanes.
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