4.6 Article

E-Zisomerization of 3-benzylidene-indolin-2-ones using a microfluidic photo-reactor

Journal

RSC ADVANCES
Volume 10, Issue 48, Pages 28630-28634

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra05288d

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Funding

  1. Council of Scientific & Industrial Research (CSIR), New Delhi
  2. Department of Science and Technology, New Delhi (Govt. of India) (DST), New Delhi [DST/INSPIRE/04/2016/000247, ECR/2017/000208]

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Here, we report controlledE-Zisomeric motion of the functionalized 3-benzylidene-indolin-2-ones under various solvents, temperature, light sources, and most importantly effective enhancement of light irradiance in microfluidic photoreactor conditions. Stabilization of theE-Zisomeric motion is failed in batch process, which might be due to the exponential decay of light intensity, variable irradiation, low mixing, low heat exchange, low photon fluxetc.This photo-mu-flow light driven motion is further extended to the establishment of a photostationary state under solar light irradiation.

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