Journal
RSC ADVANCES
Volume 10, Issue 48, Pages 28516-28522Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ra05165a
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Funding
- JSPS KAKENHI [JP16H06507, JP18H03927, JP18K19128]
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Nanoparticles composed of molybdenum oxide, MoOx, were successfully prepared by room-temperature ionic liquid (RTIL)/metal sputtering followed by heat treatment. Hydroxyl groups in RTIL molecules retarded the coalescence between MoO(x)NPs during heat treatment at 473 K in air, while the oxidation state of Mo species in MoO(x)nanoparticles (NPs) could be modified by changing the heat treatment time. An LSPR peak was observed at 840 nm in the near-IR region for MoO(x)NPs of 55 nm or larger in size that were annealed in a hydroxyl-functionalized RTIL. Photoexcitation of the LSPR peak of MoO(x)NPs induced electron transfer from NPs to ITO electrodes.
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