Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 68, Pages 9854-9857Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc04661b
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Funding
- National Natural Science Foundation of China [21402037]
- Natural Science Foundation of Hebei Province [B2019201081, B2019201101]
- Project of Introduction of Overseas Personnel in Hebei Province [C20190503]
- Advanced Talents Incubation Program of the Hebei University [801260201299]
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A novel and efficient NHC-catalyzed [3+3] annulation of enals with pyrrol-4-ones was developed, thus providing the dihydropyrano[3,2-b]pyrrol-5-one core structures with broad scope and good to excellent enantioselectivities. Notably, this strategy could also expand to the synthesis of axially chiral compounds and polysubstituted indoles.
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