Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 68, Pages 9779-9782Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc04138f
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Funding
- National Cancer Institute [R01 CA090689]
- National Science Foundation [CHE1808475]
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Product analysis from the iron Fenton oxidation of 2'-deoxyguanosine found reactions in bicarbonate buffer yield 8-oxo-2'-deoxyguanosine and spiroiminodihyantoin consistent with CO3 center dot-. Reactions in phosphate buffer furnished high yields of sugar oxidation products consistent with HO center dot. These observations change the view of DNA oxidation products from the iron-Fenton reaction.
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