4.5 Article

Rational design of metal boron imidazolate cages to frameworks

Journal

INORGANICA CHIMICA ACTA
Volume 460, Issue -, Pages 89-92

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.ica.2016.09.023

Keywords

Boron; Imidazolate; Metal-organic framework

Funding

  1. NSFC [21425102, 21601180]
  2. CAS [XDA07070200]

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The targeted construction strategy for discrete metal boron-imidazolate cages to 2D frameworks is successfully realized by tetradentate boron-imidazolate acting as cage ligands and bridge linker of frameworks. This work may help us to understand the formation mechanism of extended open frameworks. Also, the cubic cages exhibited the photocatalytic behaviour of MB. (C) 2016 Elsevier B.V. All rights reserved.

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