4.7 Article

Significant centre metallic effects on the sensing properties of two isostructural lanthanide metal-organic frameworks

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 79, Issue -, Pages 12-16

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2017.03.012

Keywords

Ln-MOFs; Small organic molecule; Nitroaromatic explosives; Sensing properties

Funding

  1. NSF of China [21373122, 21673127, 91022013, 21371089]
  2. technology innovation team support programs of Henan Province Universities [14IRTSTHN008]

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Two isostructural Ln-MOFs, [H2N(CH3)(2)][Ln(cppa)(2)(H2O)(2)] (Ln = Tb/Eu CTGU-1Tb/-1Eu, H(2)cppa = 5-(4carboxyphenyl)picolinic acid), were selected to investigate the effects of the different metal centre on the sensing properties. CTGU-1Eu can detect small organic molecule acetone and nitroaromatic explosives in water, whereas CTGU-1Tb can only detect explosive nitrophenol in water. (C) 2017 Elsevier B.V. All rights reserved.

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