4.7 Article

Photocatalytic Hydrogen Production Using a Red-Absorbing Ir(III) Co(III) Dyad

Journal

INORGANIC CHEMISTRY
Volume 56, Issue 18, Pages 10875-10881

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b00684

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Funding

  1. Region Wallonne, Belgium
  2. Universite catholique de Louvain, Belgium
  3. Prix Pierre et Colette Bauchau, Belgium
  4. Natural Sciences and Engineering Research Council, Canada
  5. Direction des Affaires Internationales de l'Universite de Montreal, Canada
  6. Wallonie Bruxelles International program

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The synthesis of a Ir(III) - Co(III) dyad with vectorial electron transfer afforded a novel supramolecular system that photocatalytically produces hydrogen in a range extending from the blue region of the spectrum to the red region with higher turnover number and frequency compared to other bimetallic dyads.

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