Journal
INORGANIC CHEMISTRY
Volume 56, Issue 11, Pages 6039-6043Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b00768
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Funding
- Nano-Material Technology Development Program [NRF-2016M3A7B4909246]
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [NRF-2016R1C1B1008452]
- Basic Science Research Program through the NRF - Ministry of Education [NRF-2015R1D1A1A01057396]
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Novel salen-Al/triarylborane dyad complexes were prepared and characterized with their corresponding mononuclear compounds. The UV-vis and photoluminescence experiments for dyads exhibited photoinduced energy transfer from borane to the salen-Al moiety in an intramolecular manner. Theoretical calculation and fluoride titration results further supported these intramolecular energy-transfer features.
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