Journal
INORGANIC CHEMISTRY
Volume 56, Issue 6, Pages 3414-3420Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b02855
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Funding
- National Key Projects for Fundamental Research and Development of China [2016YFB0600902]
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The materials Ag@MIL-100(Fe) and Ag@UI0-66(Zr) are obtained for the capture and transformation ' of CO, into alkynyl carboxylic acids, which are environmental friendly, facile to synthesize, and exhibit excellent efficiency and reusability. The influence on the catalytic activity of such Ag@MOF systems by metal-organic frameworks ' (MOFs) surface area, thermal, and chemical stability, especially the acid-base characteristics of the pores, are compared and discussed systematically.
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