Journal
INORGANIC CHEMISTRY
Volume 56, Issue 19, Pages 11810-11818Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b01775
Keywords
-
Categories
Funding
- MICINN [MAT2016-77608-C3-1-P, MAT2016-75883-C2-1-P]
- Generalitat Valenciana [PrometeoII/2014/076]
- ISIC
- MINECO [RYC-2015-17730]
Ask authors/readers for more resources
The use of theoretical calculations has allowed us to predict the coordination behavior of dithiolene [M(SC6H4S)(2)](2-) (M = Ni, Pd, Pt) entities, giving rise to the first organometallic polymers {[K-2(mu-H2O)(2)][Ni(SC6H4S)(2)]}n and {[K-2(mu-H2O)(2)(thf)](2)[K-2(mu-H2O)(2)(thf)(2)][Pd-3(SC6H4S)(6)]}(n) by one-pot reactions of the corresponding d10 metal salts, 1,2-benzenedithiolene, and KOH. The polymers are based on sigma,pi interactions between potassium atoms and [M(SC6H4S)(2)](2-) (M = Ni, Pd) entities. In contrast, only s interactions are observed when the analogous platinum derivative is used instead, yielding the coordination polymer {[K-2(mu-thf)(2)][Pt(SC6H4S)(2)]}(n).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available