4.7 Article

Long-lasting ultraviolet-A persistent luminescence and photostimulated persistent luminescence in Bi3+-doped LiScGeO4phosphor

Journal

INORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 17, Pages 3063-3071

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qi00578a

Keywords

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Funding

  1. National Natural Science Foundation of China [51902184]
  2. Shandong Provincial Natural Science Foundation [ZR2019BEM028]
  3. Shandong University [31370088963167]
  4. Natural Science Foundation of Jiangsu Province [BK20180230]
  5. China Postdoctoral Science Foundation [2018M632673]
  6. Fundamental Research Funds of Shandong University [2019JCG004]

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Persistent phosphors emitting in the ultraviolet (UV) spectral region have attracted great attention in recent years, owing to their promising potential in many advanced applications ranging from photocatalysis to phototherapy. Here, we report the development of a novel UVA emissive persistent phosphor by doping Bi(3+)into a LiScGeO(4)host. The LiScGeO4:Bi(3+)persistent phosphor can be effectively charged using a standard 254 nm UV lamp and emits intense, long-lasting persistent luminescence peaking at 365 nm for longer than 120 h. Besides, the UVA persistent luminescence from the pre-irradiated LiScGeO4:Bi(3+)phosphor can be repeatedly rejuvenated by short-time photostimulation with low-energy white, red and near-infrared (NIR) light. The long-lasting UVA afterglow, together with the photostimulated persistent luminescence (PSPL) capability, makes the LiScGeO4:Bi(3+)phosphor an important element of persistent luminescence materials in the UVA spectral region. This UVA persistent phosphor is expected to find exciting applications in the fields of medical therapy and environmental research.

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