Journal
INORGANIC CHEMISTRY
Volume 56, Issue 23, Pages 14682-14687Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b02586
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Funding
- Macquarie University
- University of New South Wales
- Australian Research Council
- Australian Research Council's Discovery Projects funding scheme [DP130101838]
- Australian Government
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Rhodium(I) complexes were explored as catalysts for the hydrogen borrowing reactions of amines and alcohols. Bidentate carbene-triazole ligands were readily synthesized via click reactions which allowed a diversity of ligand backbones to be accessed. The catalytic transformations are highly efficient, able to reach completion in under 6 h, and promote C-N bond formation across a range of primary alcohol and amine substrates. Moreover, site-selective catalysis can be achieved using substrates with more than one reactive site. A rhodium(I) complex covalently attached to a carbon black surface was also deployed in the hydrogen borrowing coupling reaction of aniline with benzyl alcohol. This represents the first report of a heterogeneous rhodium catalyst used for hydrogen borrowing.
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