Journal
INORGANIC CHEMISTRY
Volume 56, Issue 22, Pages 13634-13637Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.7b02148
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Funding
- Taishan Scholar Foundation [ts201511019]
- National Natural Science Foundation of China [21371179, 21571187]
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An amino-functionalized doubly interpenetrated microporous zinc metal-organic framework (UPC-30) has been solvothermally synthesized. UPC-30 can be stable at 190 degrees C and confirmed by powder X-ray diffraction. Gas adsorption measurements indicate that UPC-30 exhibits high H-2 adsorption heat and CO2/CH4 separation efficiency. After the exchange of Me2NH2+ by Li+ in the channels, the H-2 adsorption heat increased by 19.7%. Because of the existence of -NH2 groups in the channels, UPC-30 can effectively catalyze Knoevenagel condensation reactions with high yield and pore-size-dependent selectivity.
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