Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 18, Pages 2612-2617Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00320d
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Funding
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDA12020375, XDA12050411]
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In this study, a palladium-catalyzed [4 + 3] dearomatizing cycloaddition of N-iminoquinolinium ylides has been developed for the construction of saturated seven-membered ring in good yields. This approach features mild reaction conditions and good functional group tolerance. Furthermore, gram-scale preparation and transformation were carried out, which further underscored its synthetic utility and applicability.
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