Journal
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Volume 76, Issue -, Pages 1535-+Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S2056989020011445
Keywords
crystal structure; 4-aminopyridinium; thiocyanate; 4-aminopyridine; hydrogen bonding
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In the crystals of the title compound, C5H7N2+center dot CNS-center dot C5H6N2, the components are linked by three N-H center dot center dot center dot N and two N-H center dot center dot center dot S hydrogen bonds, resulting in two interpenetrating three-dimensional networks. Hirshfeld surface analysis shows that the most important contributions to the crystal packing are from H center dot center dot center dot H (36.6%), C center dot center dot center dot H/H center dot center dot center dot C (20.4%), S center dot center dot center dot H/H center dot center dot center dot S (19.7%) and N center dot center dot center dot H/H center dot center dot center dot N (13.4%) interactions.
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