4.7 Article

Photochromic organic cage-encapsulated Au nanoparticles: light-regulated cavities for catalytic reduction of 4-nitrophenol

Journal

DALTON TRANSACTIONS
Volume 49, Issue 35, Pages 12145-12149

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt02044c

Keywords

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Funding

  1. National Natural Science Foundation of China [21771089, 21905116]
  2. Fundamental Research Funds for the Central Universities [JUSRP51725B, JUSRP21936, JUSRP11930]
  3. Natural Science Foundation of Jiangsu Province [BK20190614]
  4. project for Jiangsu scientific and technological innovation team
  5. MOE & SAFEA for the 111 Project [B13025]
  6. Central Laboratory, School of Chemical and Material Engineering, Jiangnan University

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A diarylethene-based photochromic cage (DPC) with an adjustable cavity upon irradiation with UV and visible light has been designed and synthesized. Au nanoparticles encapsulated in the organic cage with open and closed states (Au@o-DPC and Au@c-DPC) showed different catalytic activities for the reduction of 4-nitrophenol.

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