4.7 Article

Controlling photocatalytic reduction of CO2 in Ru(ii)/Re(i) dyads via linker oxidation state

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 73, Pages 10750-10753

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc04597g

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Electronic communication between the linked metal centers in Ru(ii)-Re(i) dyads is tuned using the oxidation state (S and SO2) of sulfur-bridged ligands. Higher catalytic activity is seen for the SO2-bridged dyad in the photocatalytic reduction of CO2.

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