4.7 Article

Experimental investigation of Mg(B3H8)2 dimensionality, materials for energy storage applications

Journal

DALTON TRANSACTIONS
Volume 49, Issue 35, Pages 12168-12173

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt02170a

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Funding

  1. Swiss National Science Foundation [200020_182494, 200021_169033, CRSII2_160749]
  2. Swiss National Science Foundation (SNF) [200020_182494, 200021_169033, CRSII2_160749] Funding Source: Swiss National Science Foundation (SNF)

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Mg(B3H8)(2) is a crucial reaction intermediate in the thermal decomposition of the hydrogen storage material Mg(BH4)(2) and is discussed as a potential solid-state Mg-ion conductor. We successfully synthesized unsolvated Mg(B3H8)(2) and highlight that Mg (B3H8)(2) exists mainly as a low-dimensional solid. In addition, the Mg2+ conductivity was evaluated to be 1.4.10(-4) S cm(-1) at 80 degrees C.

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