Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 18, Pages 2628-2633Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00714e
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Funding
- National Natural Science Foundation of China [91753111, 21976112, 21775092, 21605097]
- Key Research and Development Program of Shandong Province [2018YFJH0502]
- Natural Science Foundation of Shandong Province of China [ZR2018JL008]
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A novel metal-catalyzed cascade reaction of a stable low-molecular-weight vinyl azide surrogate bearing a beta-oxygen substituent in a general fashion was disclosed. The orderly insertion of S-/O-nucleophiles and alkynes, for the first time, successfully afforded a diverse range of sulfuryl-substitutedN-vinyl-1,2,3-triazoles in good yields.
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