Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 8, Issue 37, Pages 19573-19587Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ta05827k
Keywords
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Funding
- Federal Ministry of Education and Research through the project Meet HiEnD II [03XP0084B]
- European Commission via the H2020 IMAGE project [769929-IMAGE-H2020-GV-2016-2017/H2020-GV-2017]
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An optimized dosage of (2-cyanoethyl)triethoxysilane (TEOSCN), is investigated as the electrode/electrolyte interface (EEI) modulating electrolyte additive to improve electrochemical performance of LiN0.6Mn0.2Co0.2O2(NMC622)/silicon(Si)-graphite(Gr) battery cells at a high temperature (45 degrees C). The addition of 1 wt% of TEOSCN to 1 M LiPF(6)in EC:DEC + 5 wt% FEC/2 wt% VC electrolyte is found to significantly improve the long-term cyclability, capacity retention and coulombic efficiency of NMC622/Si-Gr cells at 45 degrees C. Pouch cells cycled in a nitrile-functionalized silane bearing electrolyte show superior capacity retention (similar to 75.95%) compared to those with FEC/VC (similar to 8.05%) and without additives (EC:DEC, similar to 19.23%) electrolytes at the 364(th)cycle. Chemical mimicking and X-ray Photoelectron Spectroscopy (XPS) analysis proved that the enhanced electrochemical performance is attributed to the formation of -C equivalent to N reduction/oxidation induced robust EEI layers, both on the anode and cathode compartments, thus mitigating the escorted prevailing challenges. This work provides a highly promising electrolyte additive enabling the large-scale commercial deployment of Si-containing high-energy lithium-ion full cell batteries.
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