4.8 Article

Practical and inexpensive acid-activated montmorillonite catalysts for energy-efficient CO2capture

Journal

GREEN CHEMISTRY
Volume 22, Issue 19, Pages 6328-6333

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0gc01887b

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Funding

  1. National Research Foundation (NRF) - Ministry of Science and ICT, Republic of Korea [2017M1A2A2043151]
  2. National Research Foundation of Korea [2017M1A2A2043151] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Here, we report acid-activated montmorillonite as a cheap, durable, abundant, and efficient heterogeneous catalyst to optimize the CO(2)desorption rate at low temperatures (<= 86 degrees C), eventually to significantly minimize the energy penalty of amine solutions employed for CO(2)capture. The prepared catalysts do not degrade and can be easily separated by simple filtration. Detailed characterization reveals an increase in the BET surface area, mesoporosity, and surface acidity induced by the acid-activation process. These are the key catalytic properties responsible for the superior catalytic performance.

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