Journal
CATALYSIS SCIENCE & TECHNOLOGY
Volume 10, Issue 19, Pages 6449-6463Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cy01276a
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- Deutsche Forschungsgemeinschaft (DFG) [419924354]
- LIKAT
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Chemoselective semihydrogenation of alkynes to alkenes withE- orZ-stereoselectivity is among the most important transformations in the synthesis of highly functional organic building blocks. Use of hydrogen transfer reagents instead of gaseous hydrogen represents a viable, safe alternative in many cases. This review summarises recent developments in the field using homogeneous, molecularly defined catalyst systems with focus on hydrogen sources and mechanistic aspects of the respective systems.
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