Journal
CRYSTENGCOMM
Volume 22, Issue 38, Pages 6339-6346Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ce00905a
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Funding
- NNSFC [21471125]
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A 2D coordination polymer, 1, was synthesized, characterized, and investigated with single-crystal-to-single-crystal photoreaction and thermal pyrolysis. It could undergo two-step photoaddition upon UV irradiation: at the first step, the parallel polycatenated 2D topology of the structure changed into 4-fold interpenetrating 3D nets; at the second step, a new compound with an unreported 3D net topology was formed. Upon heating, the cyclobutanes in the photoreaction product underwent a ring opening reaction. The photoluminescence of 1 was determined by its structure; it emitted green fluorescence, and after photoaddition and photopolymerization, it emitted blue fluorescence. 1 may be a photo/thermo-switchable dual-color green-to-blue fluorescence material.
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