4.7 Article

Polyoxometalate adsorbed in a metal-organic framework for electrocatalytic dopamine oxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 79, Pages 11763-11766

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc04904b

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Funding

  1. Ministry of Science and Technology (MOST) of Taiwan [MOST 107-2218-E-006-054-MY3, MOST 108-2636-E-007-007]
  2. Higher Education Sprout Project, MOE, Taiwan
  3. Yushan Young Scholar Program, under Ministry of Education (MOE), Taiwan

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A redox-active vanadium-based polyoxometalate, V10O28, was postsynthetically immobilized into a water-stable zirconium-based metalorganic framework, NU-902. The adsorbed V10O28 in NU-902 renders charge hopping in the framework in aqueous electrolytes, and the obtained V10O28@NU-902 can be used as a heterogeneous electrocatalyst for electrochemical dopamine sensors.

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