Journal
CHEMICAL SCIENCE
Volume 11, Issue 38, Pages 10331-10336Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0sc03579c
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Funding
- German Research Council (DFG) [SFB 1176]
- Fonds der Chemischen Industrie (FCI)
- Australian Research Council (ARC)
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We introduce the formation and characterization of heterometallic single-chain nanoparticles entailing both catalytic and luminescent properties. A terpolymer containing two divergent ligand moieties, phosphines and phosphine oxides, is synthesized and intramolecularly folded into nanoparticles via a selective metal complexation of Pt(II) and Eu(III). The formation of heterometallic Eu(III)/Pt(II) nanoparticles is evidenced by size exclusion chromatography, multinuclear NMR (H-1, P-31{H-1}, F-19, Pt-195) as well as diffusion-ordered NMR and IR spectroscopy. Critically, we demonstrate the activity of the SCNPs as a homogeneous and luminescent catalytic system in the amination reaction of allyl alcohol.
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