Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 80, Pages 12033-12036Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc03805a
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Funding
- Deutsche Forschungsgesellschaft [SFB1333 C2]
- German Research Foundation (DFG) [INST 40/467-1 FUGG]
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Reported herein is the coordination of rhenium complexes to tetrazine ligand in [ReCl(CO)(3)(TzPy)] [1] (TzPy = 3-(2-pyridyl)-1,2,4,5-tetrazine) and the rates of addition of different dienophiles to the tetrazine. Tetrazine coordiation lowers the Delta S(double dagger)contribution to Delta G(double dagger)for iEDDA addition.
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