4.7 Article

Organic 2,5-dihydroxy-1,4-benzoquinone potassium salt with ultrahigh initial coulombic efficiency for potassium-ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 81, Pages 12234-12237

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc05248e

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Funding

  1. Natural Science Foundation of Shaanxi Province [2019JQ-730]
  2. Natural and Scientific Programs - Education Department of Shaanxi Provincial Government [20JS105]
  3. China Postdoctoral Science Foundation [2018M633544]
  4. Postdoctoral Science Foundation of Shaanxi Province of China [2018BSHEDZZ120]
  5. Innovation Capability Support Program of Shaanxi [2018GHJD-17]

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Here, we propose a new organic 2,5-dihydroxy-1,4-benzoquinone potassium salt (K2C6H2O4) endowing an ultrahigh initial coulombic efficiency of 96% as an advanced anode for potassium-ion batteries. Theoretical calculations and experimental results suggest that K(+)can reversibly insert into this organic compound due to the flexible and stable structure of the K(2)C(6)H(2)O(4)molecule as well as fast K(+)kinetics in the selected dimethyl ether-based electrolyte.

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