4.2 Article

Green synthesis of highly stable carbon nanodots and their photocatalytic performance

Journal

IET NANOBIOTECHNOLOGY
Volume 11, Issue 4, Pages 360-364

Publisher

INST ENGINEERING TECHNOLOGY-IET
DOI: 10.1049/iet-nbt.2016.0025

Keywords

carbon; nanostructured materials; nanofabrication; catalysis; photochemistry; ultraviolet spectra; visible spectra; photoluminescence; X-ray diffraction; transmission electron microscopy; Fourier transform infrared spectra; fluorescence; dyes; green synthesis; highly stable CD; photocatalytic performance; biosynthesis route; carbon nanodots; quantum yield; Musk melon extract; naturally derived-precursor material; ultraviolet-visible spectroscopy; dynamic light scattering; photoluminescence spectroscopy; X-ray diffraction; transmission electron microscopy; Fourier transform infrared spectroscopy; FTIR spectroscopy; fluorescence; biosynthesised CD; photocatalyst material; industrial dye; methylene blue dye degradation; photocatalytic reactor; UV-vis spectroscopy; wastewater treatment; size 5 nm to 10 nm; time 60 min

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The present study reports a novel, facile, biosynthesis route for the synthesis of carbon nanodots (CDs) with an approximate quantum yield of 38.5%, using Musk melon extract as a naturally derived-precursor material. The synthesis of CDs was established by using ultraviolet-visible (UV-vis) spectroscopy, Dynamic light scattering, photoluminescence spectroscopy, X-ray diffraction, transmission electron microscopy and Fourier transform infrared (FTIR) spectroscopy. The as-prepared CDs possess an eminent fluorescence under UV-light ((ex)=365nm). The size range of CDs was found to be in the range of 5-10nm. The authors further explored the use of such biosynthesised CDs as a photocatalyst material for removal of industrial dye. Degradation of methylene blue dye was performed in a photocatalytic reactor and monitored using UV-vis spectroscopy. The CDs show excellent dye degradation capability of 37.08% in 60min and reaction rate of 0.0032min(-1). This study shows that synthesised CDs are highly stable in nature, and possess potential application in wastewater treatment.

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