Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 20, Pages 3234-3241Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00953a
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Funding
- National Natural Science Foundation of China [21772202, 21801059]
- Beijing Municipal Science & Technology Commission [Z191100007219009]
- Beijing National Laboratory for Molecular Sciences [BNLMS-CXXM-201901]
- Natural Science Foundation of Hebei Province [B2020205005]
- Education Department Foundation of Hebei Province [QN2018110]
- Science Foundation of Hebei Normal University [L2018B06]
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Rhenium-catalyzed alkylarylation of alkenes with hypervalent iodine(iii) reagents (HIRs)viadecarboxylation to access various 3,3-disubstituted indolinones andtrans-3,4-dihydroquinolinones is described. These transformations feature wide substrate scopes, good functional-group tolerance, and divergent regioselectivity. Mechanistic studies revealed a cascade sequence of decarboxylation/intermolecular radical alkylation/intramolecular radical arylation/oxidative re-aromatization.
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