Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 84, Pages 12861-12864Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc04337k
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Funding
- Chemistry Department of the University of Basel
- SNSF [200021_130263]
- Swiss National Science Foundation (SNF) [200021_130263] Funding Source: Swiss National Science Foundation (SNF)
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Herein, a novel and rationally designedortho-substituted pyridine activator is reported that reacts rapidly and selectively with cysteine thiols. It forms reduction-stable conjugates and induces large pseudocontact shifts, residual dipolar couplings and paramagnetic relaxation enhancement on both ubiquitin S57C and human carbonic anhydrase II S50C constructs under physiological conditions.
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