Journal
BATTERIES & SUPERCAPS
Volume 3, Issue 10, Pages 1112-1119Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/batt.202000078
Keywords
gel polymer electrolytes; energy storage; one-pot synthesis; lithium-ion batteries
Funding
- Sapienza University of Rome [RM11916B863810FF]
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Gel polymer electrolytes (GPEs), composed of poly(vinylidene fluoride) (PVdF), a ternary solvent of ethylene carbonate : propylene carbonate : dimethyl carbonate, and LiBOB, which are characterized by a novel composition with a fluorine-free lithium salt, are here proposed. GPEs were firstly prepared through a solution casting procedure using the ternary carbonate solution as a solvent (namedex situprepared membranes), and then activated by being immersed in a 0.7 M LiBOB-carbonate solution. Fundamental characterizations, including thermal, spectroscopical, mechanical, and electrochemical analyses, were carried out and compared before and after the activation. GPEs, having the same composition, were also prepared by using a novel procedure (namedin situprepared membranes), involving the formation of PVdF membrane and its activation by the LiBOB electrolyte, as well as subsequent electrochemical characterizations, in the same T-shape cell. Thus prepared lithium-ion batteries, employing Sn-C and LiFePO(4)electrodes, were demonstrated to exhibit a high capacity of 150 mAh g(-1) through the course of cycling.
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