Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 21, Pages 3434-3438Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00171f
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- Fundamental Research Funds for the Central Universities [DUT19LK31]
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This study reports a photocatalytic Barbier-type allylation of various aldehydes and ketones with allyl halides for the synthesis of homoallylic alcohols driven by dual titanium and photoredox catalysis. This environmentally benign process uses the organic dye 2,4,5,6-(9H-carbazol-9-yl)isophthalonitrile (4CzIPN) as a photocatalyst and Hantzsch ester (HE) as an electron donor instead of stoichiometric metallic reductants.
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