4.6 Article

Carbon Nanosheets Decorated Activated Carbon Derived from Borassus Flabellifer Fruit Skin for High Performance Supercapacitors

Journal

JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 167, Issue 14, Pages -

Publisher

ELECTROCHEMICAL SOC INC
DOI: 10.1149/1945-7111/abbfdb

Keywords

Energy Storage; Supercapacitors; Nanoscale materials; Surface modification

Funding

  1. Ministry of Human Resources AMP
  2. Development and Department of Heavy Industries, Govt. of India [7035]

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Here, we present an ingenious approach to convert bio-waste into porous carbon to fabricate a working electrode for the development of sustainable energy storage devices. Carbonization ofBorassus Flabelliferfruit skin (BFFS) in an inert atmosphere was followed by KOH activation to synthesize partially graphitic carbon nanosheets attached to the porous carbon. Surface chemistry and porosity were tuned by varying the carbonization and activation temperature to achieve excellent control of the studied physiochemical properties. The as-obtainedABFFS-derived porous carbon exhibited a specific surface area of 1750 m(2)g(-1)with distinctive morphology, showing great prospects for energy storage. The unique content of minerals inBFFSled to a highly porous architecture with a substantial volume fraction having micro- and meso-porosity. Symmetric supercapacitors were fabricated with 1 M H(2)SO(4)and EmimBF(4)(ionic liquid) as electrolytes, and the specific capacitance reached values of 202 and 208 F g(-1), respectively. The cycling stability of up to 94% at a current density of 2 A g(-1)established a fairly stable performance for the supercapacitors based on biomass-derived carbon electrodes, and therefore, confirms the potential ofBFFS-derived activated carbon for the advancement of supercapacitors based on bio-waste electrodes.

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