Journal
NANOSCALE
Volume 12, Issue 40, Pages 20710-20718Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0nr05406b
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Funding
- Fundamental Research Funds for the Central Universities [2020ZDPYMS37]
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A transition metal phosphide is an excellent candidate for supercapacitors due to its superior electrical conductivity and high theoretical capacity. In addition, compared with traditional 3D nano-materials, 2D nanosheets possess a greater specific surface area and shorter electron transport distance. In this study, a reasonable approach is proposed for the synthesis of ZIF-67 nanosheets on nickel foam with subsequent phosphorization by chemical vapor deposition (CVD) to obtain flake-like CoP combined with Ni2P (NCP/NF), in which nickel foam serves as the current collector as well as the resource of Ni to form Ni2P. Benefiting from the nanosheet array of CoP, the NCP/NF can improve the capacity of Ni2P from 0.57 C cm(-2) to 1.43 C cm(-2) at 1 mA cm(-2). Furthermore, the NPC/NF/reduced graphene oxide (RGO) asymmetric supercapacitor (ASC) shows an energy density of 26.9 mu W h cm(-2) at a power density of 0.896 mW cm(-2), and excellent cycling performance with a capacity retention of 93.75% after 5000 cycles at 10 mA cm(-2).
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