Journal
CHEMISTRYSELECT
Volume 5, Issue 41, Pages 12819-12822Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202004021
Keywords
Alkylation; Indoles; Maleimides; C− H activation; Rh(III)-Catalyzed
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Funding
- Startup Fund for PhDs of Natural Scientific Research of Zhengzhou University of Light Industry [13501050087]
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The Rh(III)-catalyzed C2-alkylation of indoles with maleimides is disclosed under additive-free conditions by employing pyridine as a removable directing group. This protocol features low catalyst loadings, simple reaction conditions and good functional group tolerance. In addition to various indoles and maleimides, arenes, pyrroles, maleates as well as ethyl acrylates are applicable substrates.
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