New blue phosphorescent heteroleptic Ir(iii) complexes with imidazole- andN-methylimidazole carboxylates as ancillary ligands

Imidazole- andN-methylimidazole carboxylate have been introduced to serve as ancillary ligands in heteroleptic Ir(iii) complexes containing 2-phenylpyridine-based main ligands, with consideration of the frontier orbital energy levels. ComplexesIr1-Ir4were synthesized and found to have LUMO levels higher than that of the corresponding Ir(iii) complex containing pyridyl carboxylate. All the synthesized Ir(iii) complexes exhibited blue phosphorescence emission maxima in the region of 465-467 nm at room temperature. Phosphorescent quantum efficiencies were increased by a factor of 1.8-6.7 by blocking the intermolecular hydrogen bonding between the imidazole carboxylate ligands of neighboring Ir(iii) complexes, which was achieved byN-methylation of the imidazole carboxylate ancillary ligand. The organic light-emitting diodes fabricated usingIr3andIr4as dopant materials in the emissive layers were found to emit blue emission with peaks at 469 and 471 nm and maximum external quantum efficiencies of 20.0 and 22.4%, respectively. Moreover, all the fabricated devices withIr3andIr4exhibited low efficiency roll-off, indicating excellent stability of the materials.