Journal
AUSTRALIAN JOURNAL OF CHEMISTRY
Volume 73, Issue 12, Pages 1296-1300Publisher
CSIRO PUBLISHING
DOI: 10.1071/CH20256
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Funding
- Australian Government Research Training Program Stipend scholarship
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An N-heterocyclic carbene-based palladium complex was successfully immobilised on the inner surfaces of hollow silica nanospheres. The external surfaces of these spheres were functionalised with a corona-canopy to produce a Type I porous liquid. To confirm the successful immobilisation of the catalytic precursor, the porous liquid system was explored using the Heck reaction as a model reaction. This work demonstrated that homogeneous catalysts can be successfully immobilised within porous liquids in principle and that the approach used could be readily adapted for the immobilisation of other systems.
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