4.7 Article

Enhanced CO2 adsorption capacity of amine-functionalized MIL-100(Cr) metal-organic frameworks

Journal

CRYSTENGCOMM
Volume 17, Issue 2, Pages 430-437

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ce01265h

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Funding

  1. Programa Pont la Caixa per a grups de recerca de la UIB, Compagnia di San Paolo
  2. European COST Action [MP1202]
  3. Spanish Ministerio de Educacion y Ciencia
  4. University of Turin [ORTO114XNH]

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Amine-functionalized metal-organic frameworks EN-MIL-100(Cr) and MMEN-MIL-100(Cr) were prepared by grafting ethylenediamine and N,N'-dimethylethylenediamine molecules, respectively, on coordinatively unsaturated chromium(III) cations in MIL-100 metal-organic frameworks. Although amine grafting results in a decrease in the surface area and pore volume of the functionalized samples compared to those of the bare MIL-100(Cr), results showed that the incorporation of amine groups into the MIL-100 framework improved both carbon dioxide adsorption capacity and kinetics, especially in the case of ethylenediamine. Heats of carbon dioxide adsorption in EN-MIL-100(Cr) and MMEN-MIL-100(Cr) were about 80 kJ mol(-1) at zero coverage, a value higher than that shown by MIL-100(Cr), which suggests chemisorption between CO2 and pendant amine groups. Measurement of CO2 adsorption-desorption cycles proved that functionalized materials show good regenerability and stability.

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