Journal
CRYSTENGCOMM
Volume 17, Issue 46, Pages 8870-8875Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce00859j
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Funding
- Russian Science Foundation [14-13-00884]
- Russian Science Foundation [14-13-00884] Funding Source: Russian Science Foundation
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We report a new family of photoactive molecular compounds for which reversible solid state transformations and linkage isomerism have been observed using in situ X-ray diffraction. The interaction of tris(triphenylphosphine)silver(I) with eicosaborate [B20H18](2-) afforded a binuclear complex with a bridging boron cluster that underwent a series of isomerization transformations occurring in a single-crystal-to-single-crystal manner without crystal degradation and obeying the criteria for an effective molecular switch.
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