Journal
GREEN CHEMISTRY
Volume 22, Issue 22, Pages 7760-7764Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0gc01725f
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Funding
- ACCEL program, Japan Science and Technology Agency (JST) [JPMJAC1501]
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The synthesis of pyrrolidones via reductive amination of levulinic acid with aniline was examined over polypyrrolidone-stabilized metal nanoparticle catalysts. Among them, Ir metal was the most effective and applicable for the reductive amination of levulinic acid with nitroarenes/nitriles. Importantly, this catalyst was used for the one-pot synthesis of the anti-inflammatory drug indoprofen from 2-formylbenzoic acid and 2-(4-nitrophenyl)propanoic acid.
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