Journal
CRYSTENGCOMM
Volume 22, Issue 44, Pages 7704-7715Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ce01274b
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Funding
- Monash University Malaysia
- University of Western Australia
- Flinders University
- Fundamental Research Grant Scheme, Ministry of Education Malaysia [FRGS/1/2018/STG07/MUSM/03/1]
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The organisation of the p-xylylenebis(triphenylphosphonium) dication in the solid state, in crystals formed under a variety of conditions, at different pH values and in the presence of THF and other potential building moieties including p-sulfonatocalix[4]arene, 1-methyl-3-butylimidazolium and aquated gadolinium(III) has been investigated using single crystal X-ray diffraction studies. Striking changes in the dication conformations (cis- and trans-) that contribute to the different crystal packings of the dication (two-dimensional layerings and three-dimensional scaffoldings) have been established for five different compounds. The interplay and the self-assembled arrays of the dication with other incorporated components and the overall non-covalent interactions have been quantified using Hirshfeld surface analyses.
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