4.7 Article

Understanding the structural properties of p-xylylenebis(triphenylphosphonium) cation under different pH and anion conditions

Journal

CRYSTENGCOMM
Volume 22, Issue 44, Pages 7704-7715

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ce01274b

Keywords

-

Funding

  1. Monash University Malaysia
  2. University of Western Australia
  3. Flinders University
  4. Fundamental Research Grant Scheme, Ministry of Education Malaysia [FRGS/1/2018/STG07/MUSM/03/1]

Ask authors/readers for more resources

The organisation of the p-xylylenebis(triphenylphosphonium) dication in the solid state, in crystals formed under a variety of conditions, at different pH values and in the presence of THF and other potential building moieties including p-sulfonatocalix[4]arene, 1-methyl-3-butylimidazolium and aquated gadolinium(III) has been investigated using single crystal X-ray diffraction studies. Striking changes in the dication conformations (cis- and trans-) that contribute to the different crystal packings of the dication (two-dimensional layerings and three-dimensional scaffoldings) have been established for five different compounds. The interplay and the self-assembled arrays of the dication with other incorporated components and the overall non-covalent interactions have been quantified using Hirshfeld surface analyses.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available