Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2020, Issue 47, Pages 4450-4453Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202000816
Keywords
CO2 reduction; Homogeneous catalyst; Nickel; Photocatalysis
Categories
Funding
- Fundamental Research Funds for the Central Universities [20lgpy87]
- Guangxi Natural Science Foundation of China [2020GXNSFAA159132]
- National Natural Science Foundation of China [22061004]
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The utilization of synergy between two metal sites in dinuclear metal catalysts for CO2 reduction remains challenging. Herein, for the first time, we employ a dinuclear nickel complex as a molecular catalyst for visible-light-driven CO2 reduction with 99 % selectivity toward CO production. The photocatalytic mechanism was proposed based on the results of electrochemical measurements and fluorescent quenching experiments.
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