4.7 Article

Sustainable 2,5-furandicarboxylic synthesis by a direct 5-hydroxymethylfurfural fuel cell based on a bifunctional PtNiSx catalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 88, Pages 13611-13614

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d0cc06087a

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Funding

  1. Natural Science Foundation of China [51902312, 51872292]
  2. young project of Anhui Provincial Natural Science Foundation [1908085QB83]
  3. China Postdoctoral Science Foundation [2019M652224]

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A nanocatalyst with an interface between Pt and NiSx on carbon black (PtNiSx/CB) was synthesized, exhibiting superior electrocatalytic activities toward the oxygen reduction reaction (ORR) and 5-hydroxymethylfurfural (HMF) oxidation reaction. Based on bifunctional PtNiSx/CB, a new type of direct HMF fuel cell was assembled, which can continuously convert HMF to value-added 2,5-furandicarboxylic acid with stable discharging performance.

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