Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 8, Issue 43, Pages 22626-22631Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0ta08067e
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Funding
- German Ministry of Education and Research (BMBF) [03XP0091]
- HyPerCells graduate school
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In this communication, we present the phase diagram of CsPb(BrxI1-x)(3) (0 <= x <= 1, 300-585 K) obtained by high-throughput in situ GIWAXS measurements of a combinatorial thin film library. We find that all compositions convert to the cubic perovskite phase at high temperature and that the presence of bromide in the films stabilizes the metastable perovskite phases upon cool down. In accordance with recent predictions from DFT-calculations, the transition temperatures monotonically decrease with increasing bromide content.
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