Journal
CRYSTALS
Volume 10, Issue 11, Pages -Publisher
MDPI
DOI: 10.3390/cryst10110993
Keywords
single crystals; organic semiconductors; charge transfer cocrystals; the degree of charge transfer; conductivity; mobility
Funding
- National Natural Science Foundation of China [11704311, 51803168]
- Nowthwest University
- Youth Innovation Team of Shaanxi Universities
- Natural Science Foundation of Shaanxi Provincial Department of Education [17JK0772]
- Natural Science Foundation of Shaanxi Province [2018JQ1069]
- National Research Foundation, Prime Minister's Office, Singapore under its Campus of Research Excellence and Technological Enterprise (CREATE) programme
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Organic charge-transfer cocrystals (CTCs) have attracted significant research attention due to their wide range of potential applications in organic optoelectronic devices, organic magnetic devices, organic energy devices, pharmaceutical industry, etc. The physical properties of organic charge transfer cocrystals can be tuned not only by changing the donor and acceptor molecules, but also by varying the stoichiometry between the donor and the acceptor. However, the importance of the stoichiometry on tuning the properties of CTCs has still been underestimated. In this review, single-crystal growth methods of organic CTCs with different stoichiometries are first introduced, and their physical properties, including the degree of charge transfer, electrical conductivity, and field-effect mobility, are then discussed. Finally, a perspective of this research direction is provided to give the readers a general understanding of the concept.
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