Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 23, Pages 3956-3966Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0qo00987c
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Funding
- National Key Research and Development Program of China [2017YFD0200500]
- NSFC [21971065, 21722202, 21672069, 21871089]
- STCSM [20XD1421500, 20JC1416800, 18JC1415600]
- Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning, and Innovative Research Team of High-Level Local Universities in Shanghai [SSMU-ZLCX20180501]
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Sulfonyl compounds have attracted considerable interest due to their extensive applications in drug discovery. Access to the assembly of SO2-containing compounds via the oxygenation oxidative-state introduction of hypervalent sulfur has come to the fore in recent years. This review discusses the application of the same oxygenation-state introduction of hypervalent sulfur strategy under transition-metal-free conditions, and presents it in light of different atoms being linked to the sulfonyl group, including sulfones, sulfonamides, sulfonyl fluorides and thiosulfonates.
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