Journal
CRYSTENGCOMM
Volume 17, Issue 31, Pages 6030-6036Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ce00823a
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Funding
- National Natural Science Foundation of China [21171065, 21201077]
- Open Project of Key Laboratory (State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, College of Chemistry, Jilin University, Changchun, Jilin, PR China) [201325]
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A series of lanthanide coordination polymers (LnCPs), namely [Ln(TZI) (H2O)(5)](n) (1-5) [Ln = Nd (1), Eu (2), Gd (3), Tb (4) and Sm (5)], were synthesized through the self-assembly of 5-(1H-tetrazol-5-yl)isophthalic acid (H(3)TZI) ligand and lanthanide ions. X-ray crystallographic analysis reveals that compounds 1-5 are isostructural, featuring a 1D double-chain structure. The luminescence spectra in the solid state reveal that compounds 2 and 4 exhibit the characteristic luminescence of Eu(III) and Tb(III) ions, respectively, while compound 3 exhibits much enhanced blue-green emission which is derived from the H(3)TZI ligand. Further, by introducing single dopant Eu(III) and codopants Eu(III)/Tb(III) into the Gd(III) framework, white light emission and color-tunable luminescence from yellow to blue were realized.
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